In general yes it should be possible, but you did not share a lot of information to answer the question ...
Do you already have ADFS servers? Do you use Azure MFA there already? Do you use Azure MFA already for another service in your company or do you plan to implement it completely new?
Does your company in this case already uses an Azure AD and/or Office 365 or other Microsoft Cloud Services? Or what is the exact reason to use Azure MFA if there are no prerequisites?
ADFS technically is a SAML Identity Provider (I assumed you use this one as it is probably the only SAML IdP with an Azure MFA Integration). Another way you can go is with a Microsoft NPS RADIUS Server with the Azure MFA Plugin.
Is it possible for you that you connect other cloudservices (salesforce, dropbox business, ...) with SAML (with the existing things that you already have with your microsoft subscriptions)? If yes, then I you should be able to configure GP the same way as other SAML cloud services ... if not, you probably need ADFS ...
Yes earlier today i exported the SAML xml file in PA.
Then i try to connect to the Client everytime i see the error message in system logs of PA
|'SAML SSO authentication failed for user \'\'. Reason: SAML web single-sign-on failed. reply message \'Reason: SAML web single-sign-on failed.\'' )|
Did you follow the help documents from paloalto and microsoft (https://docs.microsoft.com/en-us/azure/active-directory/manage-apps/configure-single-sign-on-non-gal...) to configure this?
This error message sounds very generic. When did it show up?
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